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Publications 1981-1985

  1. A.C. Barefoot, E.W. Corcoran, R.P. Hughes, D.M. Lemal,
    W.D. Saunders, B.B. Laird, and R.E. Davis,
    Octafluorocyclooctatetraene Transition Metal Chemistry;
    1,2-η and 1,2,3,6-η-Complexes of Iron and Platinum,
    J. Am. Chem. Soc., 1981, 103, 970.
  1. P.R. Clemens, R.P. Hughes, and L.D. Margerum,
    The Stereochemical Features of the 1,3-Chloropalladation
    of Bicyclic Methylenecyclopropanes,
    J. Am. Chem. Soc., 1981, 103, 2428.
  1. W.A. Donaldson and R.P. Hughes,
    The Direct Measurement of 1J(13C-13C) in a
    Coordinated Cyclobutadiene Ligand,
    J. Magn. Reson., 1981, 43, 170.
  1. P.J. Desrosiers and R.P. Hughes,
    Allylic Rearrangements in the Thermal Decarbonylation of
    2-Cyclopropene-1-carbonyl Rhenium Compounds,
    J. Am. Chem. Soc., 1981, 103, 5593.
  1. W.A. Donaldson and R.P. Hughes,
    A Convenient Synthesis of
    2-Alkyl-3-deutero-2-cyclopropene-1-carboxylic Acids,
    Synth. Commun., 1981, 11, 999.
  1. R.P. Hughes,
    The Organic Chemistry of Rhodium,
    Comprehensive Organometallic Chemistry, Sir G. Wilkinson,
    F.G.A. Stone, E.W. Abel, Eds., Pergamon Press (Oxford), 1982.
  1. T.A. Albright, P.R. Clemens, R.P. Hughes, D.E. Hunton,
    and L.D. Margerum,
    The Chloropalladation of Alkyl-Substituted Methylenecyclopropanes,
    J. Am. Chem. Soc., 1982, 104, 5369.
  1. B.K. Dallas, R.P. Hughes, and K. Schumann,
    The Chloropalladation of
    Phenyl-Substituted Methylenecyclopropanes,
    J. Am. Chem. Soc., 1982, 104, 5380.
  1. R.P. Hughes and C.S. Day,
    Steric Blocking of η3→η1→η3 Isomerizations of a η3-Allylic Ligand;
    Crystal and Molecular Structures of 1,3-Chloropalladation Products of cis -9-Methylenebicyclo[6.1.0]nonane and
    cis -7-Methylenebicyclo[4.1.0]heptane,
    Organometallics, 1982, 1, 1221.
  1. D.M. DeSimone, P.J. Desrosiers, and R.P. Hughes,
    2-Cyclopropene-1-carbonyl Complexes of Rhenium, Manganese,
    and Iron;
    A Facile Route to Nonfluxional 2-Cyclopropenyl Rhenium Compounds,
    J. Am. Chem. Soc., 1982, 104, 4842.
  1. W.A. Donaldson and R.P. Hughes,
    The Mechanism of Formation of Oxocyclobutenyl Cobalt Compounds
    from [Co(CO)4] and Cyclopropenium Cations,
    J Am. Chem. Soc., 1982, 104, 4846.
  1. B.E. Boland-Lussier, M.R. Churchill, R.P. Hughes,
    and A.L. Rheingold,
    Synthesis of Cationic Vinylidene Complexes of Iron;
    Formation of C-N and C-P Bonds and the Crystal and Molecular
    Structure of [Fe(η-C5H5)(CO)(PPh3){C(PPh3)=CH2}]+BF4,
    Organometallics, 1982, 1, 628.
  1. B.E. Boland-Lussier and R.P. Hughes,
    Reactions of the Cationic Vinylidene Compound
    [Fe(η-C5H5)(CO)(PPh3)(C=CH2)]+BF4
    with O-H, N-H, S-H, Cl-H, and C=C Bonds,
    Organometallics, 1982, 1, 635.
  1. W.A. Donaldson, R.P. Hughes, R.E. Davis, and S.M. Gadol,
    Synthesis of Cationic and Zwitterionic Cyclobutadiene Compounds of Cobalt(I); Crystal and Molecular Structure of
    Tricarbonyl(η-1-methoxy-3-methyl-2-phenylcyclobutadiene)cobalt(+1) Hexafluorophosphate,
    Organometallics, 1982, 1, 812.
  1. R.P. Hughes, J.M.J. Lambert, J.W Reisch, and W.L. Smith,
    Reinvestigation of Some Reactions of
    Metal Carbonyl Anions with Cyclopropenium Cations;
    Conversion of η3-Cyclopropenyl to η3-Oxocyclobutenyl Ligands,
    Organometallics, 1982, 1, 1403.
  1. R.P. Hughes, D.E. Samkoff, R.E. Davis, and B.B. Laird,
    Octafluorocyclooctatetraene Transition Metal Compounds;
    Novel Transannular Ring Closures and a Formal Intramolecular Redox Equilibrium between 1,2,5,6-η and 1,2,3,6-η Ligands,
    Organometallics, 1983, 2, 195.
  1. S.J. Doig, R.P. Hughes, S.L. Patt, D.E. Samkoff, and W.L. Smith,
    Octafluorocyclooctatetraene Transition Metal Compounds;
    Displacement of Fluoride by Metal Carbonyl Anions,
    J. Organomet. Chem., 1983, 250, C1.
  1. R.P. Hughes, J.W. Reisch, and A.L. Rheingold,
    A Novel Synthetic Route to Cyclobutadiene Complexes
    of Molybdenum and  Tungsten;
    Crystal and Molecular Structure of Mo(η-C5H5)(η-C4Ph3Me)(CO)Cl,
    Organometallics, 1984, 3, 1761.
  1. S.J. Doig, R.P. Hughes, R.E. Davis, S.M. Gadol, and K.D. Holland,
    Cobalt Complexes of Hexafluorodehydrocyclooctatetraene:
    Synthesis and Crystal and Molecular Structures of
    [Co(CO)3]2(C8F6) and [Co(CO)2(PPh3)]2(C8F6),
    Organometallics, 1984, 3, 1921.
  1. R.P. Hughes, J.W. Reisch, and A.L. Rheingold,
    The Synthesis and Crystal and Molecular Structure of an
    η-Cyclopropene Complex of Molybdenum,
    Organometallics, 1985, 4, 241.
  1. P. Paetzold, K. Delpy, R.P. Hughes, and W.A. Herrmann,
    [2+2]-Cycloaddition of an Iminoborane to a
    Methylene-Titanium Coordination Compound,
    Chem. Ber., 1985, 118, 1724.
  1. R.P. Hughes, A.L. Rheingold, W.A. Herrmann, and J.L. Hubbard,
    Formation of a Heteronuclear Cluster Containing
    Ruthenium and Rhodium;
    Crystal and Molecular Structure of [Rh(C5Me5)]3[Ru(CO)3](µ3-CO)3,
    J. Organomet. Chem., 1985, 286, 361.
  1. N.M. Doherty, B.E. Ewels, R.P. Hughes, D.E. Samkoff,
    W.D. Saunders, R.E. Davis, and B.B. Laird,
    Cyclopentadienyl Complexes of Cobalt(I) and Rhodium(I) Containing
    Valence Isomers of Octafluorocyclooctatetraene;
    Crystal and Molecular Structures of the exo- and endo-Isomers of
    (Cyclopentadienyl)(Octafluorobicyclo[4.2.0]octa-2,4,7-triene)-
    rhodium(I),
    Organometallics, 1985, 4, 1606. 
  1. R.P. Hughes, J.W. Reisch, and A.L. Rheingold,
    Oxidative Addition of Cyclopropenyl Cations to Zerovalent
    Molybdenum and  Tungsten Centers; Crystal and Molecular Structures of Two Cyclopropenyl Complexes of Molybdenum(II),
    Mo(C5H5)(C3Ph2R)(CO)2 {R = Ph, tBu},
    Organometallics, 1985, 4, 1754.
  1. R.P. Hughes, W. Kläui, J.W. Reisch, and A. Müller,
    Reactions of Cyclopropenyl Cations with Group 6 Metal Carbonyl
    Anions; Formation of η3-Oxocyclobutenyl Complexes
    of Molybdenum and Tungsten,
    Organometallics, 1985, 4, 1761.
  1. R.P. Hughes, J.M.J. Lambert, and A.L. Rheingold,
    A Novel Transition Metal Promoted Rearrangement of a
    Cyclopropenyl Cation. Synthesis and Crystal and
    Molecular Structure of a 1,2,3-η-Butadienyl Complex of Platinum.
    Organometallics, 1985, 4, 2055.